Electrochemical and Photoelectrochemical Investigation of New Self-Assembled Films Based on Prussian Blue and a Terpyridyl RuII Complex
Bibliographic record
Abstract
A new hybrid multilayer film containing Prussian blue (PB) and a bis-terpyridyl RuII complex of RuII(L)2(ClO4)2 (in which L = 4'-(4-(imidazol-1-yl)phenyl)-2,2':6',2"-terpyridine), was fabricated though covalently and electrostatic layer-by-layer self-assembly techniques, and characterised by UV-vis absorption spectroscopy, cyclic voltammetry, and photoelectrochemical techniques. The results demonstrated that the two film-forming components were successfully transferred into the hybrid film, which exhibited three quasi-reversible redox couples centred at 0.06, 0.76, and 1.0 V. The photoelectrochemical studies showed that an 11-layer film exhibited a large cathodic photocurrent density of 7.72 µA cm–2 while irradiated with 100 mW cm–2 polychromatic light (325 < ? < 730 nm) at an applied potential of –0.2 V versus a saturated calomel electrode.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".