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Record W2086284626 · doi:10.1002/cjce.20181

Separation of VOCs from N<sub>2</sub> using poly(ether block amide) membranes

2009· article· en· W2086284626 on OpenAlexafffundvenue
Li Liu, A. Chakma, Xianshe Feng, Darren Lawless

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2009
Typearticle
Languageen
FieldEngineering
TopicMembrane Separation and Gas Transport
Canadian institutionsMonteco (Canada)University of Waterloo
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsPermeanceChemistryMembraneNitromethaneMethanolAcetoneEtherHexaneMembrane technologyAlcoholPermeationOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract This work deals with the separation of volatile organic compounds (VOCs) from nitrogen streams for organic vapour emission control by poly(ether block amide) membranes. As representative air pollutant VOCs, n ‐pentane, n ‐hexane, cyclohexane, n ‐heptane, methanol, ethanol, n ‐propanol, n ‐butanol, acetone, dimethyl carbonate, and methyl tert ‐butyl ether were used in this study. The separation of both binary VOC/N 2 and multicomponent VOCs/N 2 gas mixtures was carried out, and the membranes exhibited good separation performance. A VOC concentration of more than 90 mol% was achieved at a feed VOC concentration of 5 mol%. It was found that the permeances of the VOCs were mainly dominated by their solubilities in the membrane, whereas the permeance of N 2 was affected by the presence of the VOCs. The permeance of N 2 in the VOC/N 2 mixtures was shown to be higher than pure N 2 permeance due to membrane swelling induced by the VOCs dissolved in the membrane. Nevertheless, theVOC/N 2 selectivity increased with an increase in the feed VOC concentration. Among the VOCs studied, the membrane showed a higher permeance to alcohol VOCs than paraffin VOCs. The effects of feed VOC concentration, temperature, stage cut, and permeate pressure on the separation performance were investigated.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.211
Threshold uncertainty score0.543

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.205
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations43
Published2009
Admission routes3
Has abstractyes

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