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Record W2090618002 · doi:10.1021/jp013541z

Propagation of Excitation Pulses and Autocatalytic Fronts in Packed-Bed Reactors

2002· article· en· W2090618002 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueThe Journal of Physical Chemistry B · 2002
Typearticle
Languageen
FieldComputer Science
TopicNonlinear Dynamics and Pattern Formation
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsMechanicsFlow velocityTurbulenceExcitationPacked bedPhysicsFlow (mathematics)Chemistry

Abstract

fetched live from OpenAlex

We experimentally and numerically studied the velocity of excitation pulses in packed bed flow reactors as a function of the fluid flow velocity and the diameter of the glass beads used as packing material. Differential transport was absent. The downstream and upstream propagating pulses were observed to behave in a manner that is strikingly different from the simple Galilean translation expected in the case of an ideal homogeneous plug-flow. Downstream propagating pulses travel faster than anticipated, by a constant factor that depends on the bead size. Upstream propagating pulses travel at a lower velocity and become stationary above a critical value of the fluid flow velocity. Both the width and the intensity of up- and downstream propagating pulses increase when the fluid flow velocity is increased. Model calculations show that the accelerated downstream propagation and the decelerated upstream propagation agree qualitatively with enhanced turbulent diffusion within the packed bed. The formation of stationary pulses can be explained by the existence of a stationary fluid phase of stagnant pockets within the packed bed. Once excited, a stagnant pocket acts as a permanent super-critical perturbation, which causes excitation of the flowing medium and locks the temporal response in space. The dramatic increase of the pulse-intensity remains unexplained by the mentioned models.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.851
Threshold uncertainty score0.118

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.222
Teacher spread0.210 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it