MétaCan
Menu
Back to cohort

Forensic Fibre Analysis by UV-Visible Microspectrophotometry

2010· article· en· W2092505368 on OpenAlexafffundvenue
Johanne Almer, Eleanor Mcansh, Barbara Doupe

Bibliographic record

VenueCanadian Society of Forensic Science Journal · 2010
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Chemometric Analyses
Canadian institutionsHealth Sciences Centre
FundersUniversity of Toronto Mississauga
KeywordsMaterials sciencePolyesterAbsorbancePolyvinylpyrrolidoneVisible spectrumTextileQuartzSpectrophotometryPolymerUltravioletAnalytical Chemistry (journal)Composite materialChemistryPolymer chemistryChromatographyOptoelectronics

Abstract

fetched live from OpenAlex

This study evaluated various aspects of UV-VIS microspectrophotometry for routine colour analysis of fibres in a forensic laboratory, and was compared to visible microspectrophotometry. Quartz plates and glycerine mounting medium do not absorb within the spectral range of 240 nm to 380 nm. However, glass and XAM™ mounting medium, which are routinely used for microscopic fibre analysis and visible microspectrophotometry, were found to absorb substantially below 320 nm. The spectral interference from the polymeric composition of fibres was also studied. Wool, silk, polyester and acrylics with methylvinylpyridine(MVP) are highly absorbing below 310 nm, so dye colour analysis could not be applied in that region for these fibre types. Acetates, nylons, modacrylics and acrylics with polyvinylpyrrolidone (PVP) have low or moderate absorbance below 310 nm, which causes some interference. Cotton, rayon, and olefins do not absorb in the UV range. Analysis of glass-mounted fibres in the UV-VIS range can provide increased discrimination over analysis in the visible range. A flowchart decision tree was developed to guide the analyst in the application of UV-VIS microspectrophotometry for fibre analysis. Dyed fibres could initially be analysed under glass mount by UV-VIS microspectrophotometry from 320 nm to 770 nm. For fibre types with little or no polymeric UV spectral interference, additional spectral information could be obtained from UV-VIS analysis on quartz slides, measured from 240 nm to 770 nm.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.116
Threshold uncertainty score0.997

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.008
Science and technology studies0.0010.002
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0050.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.254
Teacher spread0.247 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations16
Published2010
Admission routes3
Has abstractyes

Explore more

Same venueCanadian Society of Forensic Science JournalSame topicSpectroscopy and Chemometric AnalysesFrench-language works237,207