Optical, Electrochemical, Magnetic, and Conductive Properties of New Poly(indolocarbazole‐<i>alt</i>‐bithiophene)s
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Abstract Summary: New alternating copolymers based on indolocarbazole (IC), both two‐ and three‐coupled, and bithiophene (BT) or bis(3,4‐ethylenedioxythiophene) (BiEDOT), were obtained using Stille or Suzuki coupling reactions. Those copolymers have been investigated by cyclic voltammetry, electrochemical quartz crystal microbalance, in situ electron spin resonance, in situ conductivity, and UV‐Vis‐NIR spectroelectrochemistry techniques. All polymer films undergo reversible oxidation processes. One to three isoelectronic oxidation processes, involving one electron per repeat unit, produce radical cations, dications, and radical trications. The oxidative charge is localized in the IC moiety for BT copolymers or over the whole polyconjugated backbone for BiEDOT copolymers. Redox neutral‐polaron conductivities are in the range of 0.02–0.1 S · cm −1 and polaron‐bipolaron conductivities in the range of 0.1–0.7 S · cm −1 . Chemical structure of the PIC derivatives. magnified image Chemical structure of the PIC derivatives.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it