Oxidation of Thallium by Freshwater Plankton Communities
Bibliographic record
Abstract
Thallium is a toxic metal that is of emerlI(I) or Tl(III), and its oxidation state affects its complexation and subsequent bioavailability and toxicity. We conducted lab and field incubations with 204Tl(I) and natural plankton assemblages to study the occurrence and mechanism of Tl oxidation. We observed that Tl(III) comprised 74% of total dissolved Tl after a 60 h incubation in surface waters from Lake Ontario, revealing a maximum specific oxidation rate of 0.014 h(-1). No Tl(I) oxidation was observed in sterile-filtered control treatments, indicating that solar radiation alone does not oxidize Tl(I) to Tl(III). Additional incubations with pond water revealed that Tl(I) oxidation is mediated by microbial activity and is not related to the presence of abiotic particles or phytoplankton or protozoa. We also identified a minor fraction (5-13%) of nonion-exchangeable (Chelex-100 resin; pH 1.5) Tl that may represent dimethylthallium or complexed thallium. This study demonstrates that planktonic bacteria are responsible for oxidizing the thermodynamically stable Tl(I) to the more abundant Tl(III).
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.000 | 0.001 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".