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Record W2096697725 · doi:10.1002/cjce.21956

Lipase immobilisation in matrix comprised of gelatin of different bloom numbers with the addition of hydrophilic plasticisers

2014· article· en· W2096697725 on OpenAlexvenueno aff
Aniela Pinto Kempka, Selene Maria de Arruda Guelli Ulson de Souza, Antônio Augusto Ulson de Souza

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2014
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicEnzyme Catalysis and Immobilization
Canadian institutionsnot available
Fundersnot available
KeywordsGelatinLipaseChemistryGlycerolMannitolChromatographyHydrolysisWater activityOrganic chemistryEnzymeWater content

Abstract

fetched live from OpenAlex

Gelatin is a low value water‐soluble protein which has the ability to form gels and its use with the addition of plasticisers has been studied in the development of biofilms. Many studies show the use of gelatin in high concentrations agent immobilisation successfully, however, most of these do not show the Bloom value of the gelatin used. In this study, lipase immobilisation in gelatin of different Bloom values with the addition of hydrophilic plasticisers, glycerol and mannitol was investigated. Mannitol showed higher efficiency for lipase immobilisation in more uniform pore structures. The immobilisation stability was affected by the pH, temperature and agitation conditions, and the matrices E8‐280‐M (corresponding to experiment 8, 280 Bloom gelatin and mannitol) and E9/10‐280‐M (corresponding to experiment 9 and 10, 280 Bloom gelatin and mannitol) were the most stable. In the hydrolysis of olive oil, the enzymatic activity of free and immobilised lipases was studied in relation to temperature, pH and time, and 42°C was found to be the optimal temperature for both forms of lipases. In terms of activity, for free lipase, the optimum pH was 7.0, for lipase immobilised in E8‐280‐M it was between 5.5 and 7.5 and for lipase immobilised in E9/10‐280‐M the optimum range was 6.5 and 7.5. Ten reuse cycles were possible, and by the 5th cycle the lipase immobilised in E8‐280‐M showed 77.66% of the initial activity. The highest retention of activity during storage was observed for the lipase immobilised at 25°C in the E8‐280‐M matrix.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.051
Threshold uncertainty score0.165

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.175
Teacher spread0.172 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2014
Admission routes1
Has abstractyes

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