Asymmetric Supercapacitors Based on Activated‐Carbon‐Coated Carbon Nanotubes
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Bibliographic record
Abstract
Abstract A new method is developed for the fabrication of asymmetric supercapacitor devices containing fibrous electrode materials. The approach is based on the synthesis of uniform polypyrrole (PPy) coatings on multiwalled carbon nanotubes (MWCNT), which were used for the fabrication of MWCNTs coated with N‐doped activated carbon (N‐AC). The N‐AC‐MWCNT electrodes show good electrochemical performance in positive and negative potential windows. The electrochemical performance of positive electrodes is further enhanced by the development of MnO 2 ‐coated N‐AC‐MWCNT. In this approach, the problem of MWCNT degradation in the reaction with KMnO 4 is avoided by the use of a sacrificial N‐AC layer, which allows a relatively high mass content of MnO 2 in the final material. The approach offers the advantages of small size of MnO 2 nanoparticles, good electrical contact of MnO 2 and MWCNT and fibrous microstructure of the material. Testing results show a remarkably high specific capacitance of 6.29 F cm −2 (311.7 F g −1 ) at a mass loading of 20 mg cm −2 . The important finding is the possibility to fabricate asymmetric devices, which show a specific capacitance of 2.19 F cm −2 (62.7 F g −1 ) in a voltage window of 1.9 V in aqueous Na 2 SO 4 electrolyte, an energy density of 26.4 mWh g −1 and a power density of 1.7 W g −1 . The electrodes and devices show good capacitance retention at high charge–discharge rates and good cycling stability. The asymmetric capacitors developed herein are promising for practical energy‐storage applications.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it