ATRP grafting of oligo(ethylene glycol) methacrylates from gold surface — Effect of monomer size on grafted chain and EO unit densities
Bibliographic record
Abstract
Oligo(ethylene glycol) methacrylate (OEGMA) was grafted from Au surface via surface-initiated atom-transfer radical polymerization (s-ATRP). The initiator density was adjusted by the mole fractions of surface-attachable ATRP initiator and diluting agent. Three OEGMA monomers of M r 300, 475, and 1100 were used. The Au surfaces before and after modification were characterized by water contact angle and ellipsometry. The effect of monomer M r and initiator density on surface chain density and EO unit density was investigated. It was found that at low initiator density (mole fraction of initiator of 2%–5%), poly(OEGMA) grafts had comparable surface chain density independent of OEGMA M r . However, at high initiator density (mole fraction of initiator >10%), poly(OEGMA) 1100 had obviously lower chain densities than poly(OEGMA) 300 and poly(OEGMA) 475 , which could be attributed to the size difference of the monomers. The short chain length and low surface chain density of poly(OEGMA) 1100 resulted in its relatively low surface EO unit density.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".