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Record W2099721442 · doi:10.1139/s04-009

Removal of dimethyl phthalate from water by UV–H<sub>2</sub>O<sub>2</sub> process

2004· article· en· W2099721442 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueJournal of Environmental Engineering and Science · 2004
Typearticle
Languageen
FieldEnvironmental Science
TopicWater Quality Monitoring and Analysis
Canadian institutionsnot available
FundersKing Fahd University of Petroleum and Minerals
KeywordsHydrogen peroxideDimethyl phthalateChemistryUltravioletIrradiationHydroxyl radicalPhotodissociationAdvanced oxidation processMercury-vapor lampNuclear chemistryPhotochemistryPhthalateRadicalCatalysisMaterials scienceOrganic chemistry

Abstract

fetched live from OpenAlex

This study aims to demonstrate the removal efficiency of dimethyl phthalate from water using the UV–H 2 O 2 photooxidation process. Pure water samples, spiked with 20 ppm dimethyl phthalate (DMP) were treated by the combined effect of UV photolysis as well as hydrogen peroxide oxidation mechanisms. In the experiments, the concentration of hydrogen peroxide was varied from 34 to 136 ppm and a low-pressure mercury UV lamp of 100 mW power output was used to provide the necessary radiation. The effects of initial concentration of H 2 O 2 , UV exposure time, pH, and temperature were investigated. The results showed that about 60% of DMP were removed directly by activation caused by UV light radiation intensity after an exposure time of 1 h. However, the removal efficiency increased when the DMP-spiked water was dosed with H 2 O 2 prior to irradiating with UV light (i.e., UV–H 2 O 2 ). More than 98% of DMP was removed after 45 min when the UV-irradiated solution was dosed with 136 ppm of H 2 O 2 . The results also showed that lowering the pH and increasing the temperature enhanced the removal of DMP by UV–H 2 O 2 process. Key words: ultraviolet light, hydrogen peroxide, hydroxyl radical, phthalates, UV–H 2 O 2 process, advanced oxidation processes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.045
Threshold uncertainty score0.737

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.192
Teacher spread0.187 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it