Plasmon mediated shape and size selective synthesis of icosahedral silver nanoparticles via oxidative etching and their 1-D transformation to pentagonal pins
Why this work is in the frame
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Bibliographic record
Abstract
A size- and shape-selective synthesis of pentagonally twinned silver icosahedral nanoparticles (AgIhNPs), one of the five platonic solid morphologies, has been developed by integrating three key factors: nuclei templating by copper, photochemical development using violet LED light and chemical oxidative etching. The presence of copper is essential for AgIhNP shape selection via the promotion of icosahedral nuclei in precursor NPs. Violet light (401-410 nm) is crucial to promote plasmonic selection of near-spherical AgIhNPs. Oxidative etching with hydrogen peroxide and photochemical reduction with citrate establishes a red-ox equilibrium for the photochemical selection of AgIhNPs. The addition of chloride ions improves size- and shape-selectivity. Finally, the demonstration of 1-D growth of AgIhNPs to pentagonal pins initiated at AgIhNP pentagonal-twinned defects highlights a universal role of twinned defects for the formation of anisotropic nanoparticles.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it