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Record W2106761371 · doi:10.1002/cplu.201500032

Synthesis and Composition‐Dependent Visible Photocatalysis of Ag/AgBr Necklace‐Like Heterostructures

2015· article· en· W2106761371 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueChemPlusChem · 2015
Typearticle
Languageen
FieldEnergy
TopicAdvanced Photocatalysis Techniques
Canadian institutionsTrinity CollegeUniversity of Toronto
FundersNational Natural Science Foundation of China
KeywordsHeterojunctionMethyl orangeRhodamine BPhotocatalysisMaterials scienceSilver bromidePhotodegradationPolyvinylpyrrolidoneVisible spectrumChemical engineeringNanotechnologyCatalysisChemistryOptoelectronicsOrganic chemistryPolymer chemistrySilver halide

Abstract

fetched live from OpenAlex

Abstract A two‐step synthesis was developed to fabricate Ag/AgBr necklace‐like nano‐heterostructures at room temperature. Multiple crystalline Ag nanowires were used as templates following an oxidation route in situ from CuBr 2 to create Ag/AgBr heterostructures. Polyvinylpyrrolidone can govern the formation of one‐dimensional Ag/AgBr necklace‐like nano‐heterostructures. The composition of the heterostructures was adjusted by changing the amount of CuBr 2 . Experimental conditions were optimized. In particular, the concentration and injection rate of copper bromide solution play an important role in controlling the oxidation of the Ag nanowires for the purpose of adjusting the morphology of the Ag/AgBr heterostructures. As a result, the heterostructures with 40 mol % AgBr displayed a regular necklace‐like morphology. Under visible‐light irradiation, Ag/AgBr necklace‐like heterostructures with AgBr molar ratios of 10 to 50 % exhibited enhanced plasmonic photocatalytic performance for the degradation of organic pollutants (methyl orange, methylene blue, and rhodamine B).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.013
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.268
Teacher spread0.249 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it