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Record W2110125545 · doi:10.1039/b704418f

Spiers Memorial Lecture : Lessons from biomineralization: comparing the growth strategies of mollusc shell prismatic and nacreous layers in Atrina rigida

2007· article· en· W2110125545 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueFaraday Discussions · 2007
Typearticle
Languageen
FieldMaterials Science
TopicCalcium Carbonate Crystallization and Inhibition
Canadian institutionsWestern University
FundersMinerva Foundation
KeywordsBiomineralizationAragoniteCalciteNucleationAmorphous calcium carbonateChitinMaterials scienceMatrix (chemical analysis)Chemical engineeringCalcium carbonateCrystallographyMineralogyNanotechnologyChemistryComposite materialChitosanOrganic chemistry

Abstract

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The mollusc shell prismatic layer of Atrina rigida is composed of an assemblage of large and relatively perfect single calcite crystals, embedded in an organic matrix. A key to elucidating basic mechanisms of mineralization is understanding the structures of the matrix, the mineral and the relations between them. The matrix that envelopes each prism (the inter-prismatic matrix) is composed mainly of glycine-rich proteins, while the matrix inside each prism (intra-crystalline matrix) is composed of a network of chitin fibers. Prisms grow by deposition of mineral particles on the chitin fibers. The mineral particles are associated with highly acidic proteins from the Asprich family, which presumably stabilize an amorphous mineral precursor. We infer that once in contact with the already formed crystalline prism, the particles crystallize by epitaxial nucleation. In nacre, sheets of beta-chitin are interspaced by silk-like proteins in a hydrated gel-like state. beta-Chitin forms a scaffold onto which the acidic proteins are adsorbed. Some of these are organized into a crystal nucleation site, where nucleation of aragonite, supposedly from colloidal amorphous calcium carbonate particles, is induced. Comparing the mechanisms of growth of the nacreous and prismatic layers can help to understand the underlying strategies of formation of mineralized structures.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.494
Threshold uncertainty score0.374

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.267
Teacher spread0.252 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it