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Record W2114828655 · doi:10.1139/v09-025

An improved neural network method for solving the Schrödinger equation

2009· article· en· W2114828655 on OpenAlexafffundvenue
Sergei Manzhos

Bibliographic record

VenueCanadian Journal of Chemistry · 2009
Typearticle
Languageen
FieldComputer Science
TopicNeural Networks and Applications
Canadian institutionsUniversité de MontréalQueen's UniversityUniversité du Québec à Montréal
FundersNatural Sciences and Engineering Research Council of CanadaCanada Research Chairs
KeywordsBasis functionHamiltonian (control theory)Curse of dimensionalityArtificial neural networkNonlinear systemBasis (linear algebra)Wave functionSchrödinger equationApplied mathematicsRadial basis functionMathematicsAlgorithmMathematical analysisComputer scienceMathematical optimizationArtificial intelligenceQuantum mechanicsPhysicsGeometry

Abstract

fetched live from OpenAlex

We propose a neural network (NN) based algorithm for calculating vibrational energies and wave functions and apply it to problems in 2-, 4-, and 6-dimensions. By using neurons as basis functions and methods of nonlinear optimization, we are able to compute three states of a 6-D Hamiltonian using only 50 basis functions. In a standard direct product basis, thousands of basis functions would be necessary. Previous NN methods for solving the Schrödinger equation computed one level at a time and optimized all of the parameters using expensive nonlinear optimization methods. Using our approach, linear coefficients in the NN representation of wave functions are determined with methods of linear algebra and many levels are computed at the same time from one set of nonlinear NN parameters. In addition, we use radial basis function neurons to ensure the correct boundary conditions. The use of linear algebra methods makes it possible to treat systems of higher dimensionality.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.006
Threshold uncertainty score0.012

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0040.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.020
GPT teacher head0.270
Teacher spread0.250 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations40
Published2009
Admission routes3
Has abstractyes

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