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Record W2119214412 · doi:10.1017/s0885715613000766

Differentiating veatchite polytypes using X-ray powder diffraction

2013· article· en· W2119214412 on OpenAlexaffabout
Ralph Rowe, Joel D. Grice, Rémy S. Poulin

Bibliographic record

VenuePowder Diffraction · 2013
Typearticle
Languageen
FieldMaterials Science
TopicX-ray Diffraction in Crystallography
Canadian institutionsLaurentian UniversityCanadian Museum of Nature
Fundersnot available
KeywordsBoraxCrystallographyPowder diffractionDiffractionMaterials scienceX-rayMineralogyGeologyOpticsChemistryPhysics

Abstract

fetched live from OpenAlex

Veatchite polytypes were properly identified from several localities relying solely on micro powder diffraction data. Diagnostic differences in their respective calculated patterns gave reliable identification results when compared with measured data. This permitted the confirmation of co-existing veatchite-1 A and -2 M on the same specimen from the Billie Mine, Inyo County, California as flat elongated crystals (-1 A ) and flat rhombic plates (-2 M ), respectively. On the specimen from the Sterling Borax Mine (Lang), type-locality for veatchite-2 M , the polytype veatchite-1 A was confirmed from radiating rhombic plates. From the type specimen for veatchite-1 A (rhombic plates), collected from the borate deposit in Emet, Turkey, an additional unknown polytype of this mineral was discovered, but lacks suitable material for a complete characterization. At the Penobsquis deposit near Sussex in New Brunswick, Canada, only veatchite-2 M was encountered. The area between 20 and 25°2 θ holds the following diffraction signatures: -1 A (two sets of double peaks at approximately 21.5 and 24.5°2 θ ), -1 M (single peaks at 20 and 23°2 θ ) and -2 M (double peaks at 20 and 23°2 θ ). The unknown polytype from Emet, Turkey differs from polytype-1 A in that same range by having single peaks at the 21.5 and 24.5° instead of double peaks.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.015

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0030.001
Science and technology studies0.0010.000
Scholarly communication0.0010.000
Open science0.0010.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.020
GPT teacher head0.261
Teacher spread0.241 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

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Citations2
Published2013
Admission routes2
Has abstractyes

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