Bibliographic record
Abstract
[82503-38-6] C10H10AgMnN2O4 (MW 385.01) InChI = 1S/2C5H5N.Ag.Mn.4O/c2*1-2-4-6-5-3-1;;;;;;/h2*1-5H;;;;;;/q;;+1;;;;;-1 InChIKey = BKOYEWVQWOTSFK-UHFFFAOYSA-N (oxidant, useful for the oxidation of polycyclic aromatics and alkynes to diketones,1 primary benzylic alcohols to aldehydes,2 secondary alcohols to ketones;2 for the oxidative coupling of amines;3 and the deoximation of oximes3) Physical Data: purple solid, decomposes at 104–105 °C.2 Solubility: sol acetone, chloroform and dichloromethane; sparingly sol benzene and pyridine.2 Analysis of Reagent Purity: elemental analysis.2 Preparative Method: pyridine (3 mol) is added to KMnO4 (1 mol) dissolved in a minimum of distilled water followed by AgNO3 (1 mol) in 1.7 L of distilled water. The purple precipitate (90%) is washed with water and then benzene. After drying over CaCl2 it is recrystallized from acetone/benzene.2 The visible spectrum resembles that of potassium permanganate and the IR displays a strong band at 900 cm−1. Handling, Storage, and Precautions: slowly reduced by polar solvents such as acetone, chloroform, and dichloromethane; less soluble, but more stable in benzene and pyridine;2 insensitive to hammer blows, but ignites above 80 °C;2 store small amounts (10–50 g) in glass vessels at or below rt.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.002 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.002 | 0.001 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.002 | 0.000 |
| Research integrity | 0.002 | 0.001 |
| Insufficient payload (model declined to judge) | 0.080 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".