Nonlinear kinetic parameter estimation for batch cooling seeded crystallization
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Bibliographic record
Abstract
Abstract Kinetic parameter estimation for most batch crystallization processes is necessary because nucleation and crystal growth kinetic parameters are often not available. The existing identification methods are generally based on simplified population balance models such as moment equations, which contain insufficient information on the crystal size distribution (CSD). To deal with these problems, a new optimization‐based identification approach for general batch cooling seeded crystallization is proposed in this study. The final‐time CSD is directly used for identification. A novel effective method for solving the population balance equation is developed and used to identify nucleation and growth kinetic parameters. Cooling crystallization of ammonium sulfate in water was experimentally investigated, where the concentration was measured by an on‐line density meter and the final‐time CSD was analyzed by a Malvern Mastersizer 2000. Kinetics for ammonium sulfate are determined based on cooling crystallization experiments. Applying these kinetics in simulation provides a good prediction of the product CSD. © 2004 American Institute of Chemical Engineers AIChE J, 50: 1786–1794, 2004
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
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Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it