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Record W2126068340 · doi:10.1007/s00220-008-0679-y

On the Localized Phase of a Copolymer in an Emulsion: Supercritical Percolation Regime

2008· article· en· W2126068340 on OpenAlexfundno aff

Bibliographic record

VenueCommunications in Mathematical Physics · 2008
Typearticle
Languageen
FieldMaterials Science
TopicBlock Copolymer Self-Assembly
Canadian institutionsnot available
FundersDivision of Mathematical SciencesUniversity of British ColumbiaPacific Institute for the Mathematical Sciences
KeywordsCopolymerSupercritical fluidPercolation (cognitive psychology)Critical exponentPhase (matter)Directed percolationPercolation thresholdPhase diagramRelaxation (psychology)

Abstract

fetched live from OpenAlex

In this paper we study a two-dimensional directed self-avoiding walk model of a random copolymer in a random emulsion. The copolymer is a random concatenation of monomers of two types, A and B, each occurring with density $${\frac{1}{2}}$$ . The emulsion is a random mixture of liquids of two types, A and B, organised in large square blocks occurring with density p and 1 − p, respectively, where p ϵ (0, 1). The copolymer in the emulsion has an energy that is minus α times the number of AA-matches minus β times the number of BB-matches, where without loss of generality the interaction parameters can be taken from the cone $${\{(\alpha,\beta)\in\mathbb {R}^2\colon\,\alpha\geq |\beta|\}}$$ . To make the model mathematically tractable, we assume that the copolymer is directed and can only enter and exit a pair of neighbouring blocks at diagonally opposite corners. In [7], a variational expression was derived for the quenched free energy per monomer in the limit as the length n of the copolymer tends to infinity and the blocks in the emulsion have size L n such that L n → ∞ and L n /n → 0. Under this restriction, the free energy is self-averaging with respect to both types of randomness. It was found that in the supercritical percolation regime p ≥ p c , with p c the critical probability for directed bond percolation on the square lattice, the free energy has a phase transition along a curve in the cone that is independent of p. At this critical curve, there is a transition from a phase where the copolymer is fully delocalized into the A-blocks to a phase where it is partially localized near the AB-interface. In the present paper we prove three theorems that complete the analysis of the phase diagram : (1) the critical curve is strictly increasing; (2) the phase transition is second order; (3) the free energy is infinitely differentiable throughout the partially localized phase. In the subcritical percolation regime p < p c , the phase diagram is much more complex. This regime will be treated in a forthcoming paper.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: Theoretical or conceptual
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.301
Threshold uncertainty score0.496

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.095
GPT teacher head0.364
Teacher spread0.269 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2008
Admission routes1
Has abstractyes

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