Water‐soluble polymers and gels from the polycondensation between cyclodextrins and poly(carboxylic acid)s: A study of the preparation parameters
Why this work is in the frame
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Bibliographic record
Abstract
Abstract Native cyclodextrins (CDx) and some of their derivatives were reacted with poly(carboxylic acid)s (PCAs) [citric acid (CTR), 1,2,3,4‐butanetetracarboxylic acid (BTCA), and poly(acrylic acid) (PAA)]. These reactions were carried out in the dry state at a temperature greater than 140°C in air or in vacuo . They resulted in water‐soluble and insoluble polymers formed by polyesterification between CDx and PCA. In this study, the parameters of the reaction were studied, and their influence on the water solubility or swellability of the obtained polymers was investigated. High reaction temperatures, high PCA/CDx molar ratios, and long reaction times preferably yielded insoluble gels, whereas softer conditions resulted in very soluble polymers. The gels could swell up to 10 times their initial volume in water, and the water‐soluble fraction had a solubility of 1 g/mL. A reaction mechanism was proposed that required the use of PCA carrying at least three neighboring carboxylic groups (CTR, BTCA, and PAA), and it was confirmed experimentally by the unsuccessful use of some dicarboxylic acids. A preliminary characterization by Fourier transform infrared spectroscopy and size exclusion chromatography was also conducted. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 433–442, 2005
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it