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Record W2126485679 · doi:10.1039/c5sm01408e

CO<sub>2</sub> foam properties and the stabilizing mechanism of sodium bis(2-ethylhexyl)sulfosuccinate and hydrophobic nanoparticle mixtures

2015· article· en· W2126485679 on OpenAlexaff
Chao Zhang, Zhaomin Li, Qian Sun, Peng Wang, Shuhua Wang, Wei Liu

Bibliographic record

VenueSoft Matter · 2015
Typearticle
Languageen
FieldMaterials Science
TopicPickering emulsions and particle stabilization
Canadian institutionsUniversity of Calgary
Fundersnot available
KeywordsNanoparticleChemical engineeringMaterials sciencePulmonary surfactantSurface tensionAdsorptionPhase (matter)BubbleDispersion (optics)Contact angleViscoelasticityZeta potentialComposite materialNanotechnologyChemistryThermodynamicsOrganic chemistryOptics

Abstract

fetched live from OpenAlex

In this work, we have prepared CO2-in-water foam by mixing partially hydrophobic SiO2 nanoparticles and sodium bis(2-ethylhexyl)sulfosuccinate (AOT) and studied its properties. The observation of the appearance of the foam revealed that, with the continuous addition of AOT, the phase behavior of the SiO2 nanoparticle and the AOT mixed system transformed from that of a two-phase system of aggregated nanoparticles into that of a uniform dispersed phase. Both foaming ability and foam stability were optimized when the nanoparticles and the AOT were mixed in a proportion of 1 : 5. On the basis of our findings from measurements of the dispersion properties, including measurements of the adsorption isotherm of the surfactant on the nanoparticles, zeta potentials, interfacial tension and the three-phase contact angle, we concluded that the synergistic interactions between the SiO2 nanoparticles and the AOT led to the adsorption of nanoparticles around the bubble surface and the formation of a spatial network structure of nanoparticles in the film, thereby enhancing the mechanical strength of the bubble and improving the resistance to outside disturbances, deformation and drainage. Laser scanning confocal microscopy (LCSM) analysis of the same foams further confirmed the existence of a "viscoelastic shell" wrapped around and protecting the bubble.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.025
GPT teacher head0.226
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations107
Published2015
Admission routes1
Has abstractyes

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