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Record W2132570398 · doi:10.1002/prep.200400096

Characterization of ADN and ADN‐Based Propellants

2005· article· en· W2132570398 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenuePropellants Explosives Pyrotechnics · 2005
Typearticle
Languageen
FieldEngineering
TopicEnergetic Materials and Combustion
Canadian institutionsCanadian Nuclear Laboratories
FundersDefence Research and Development Canada
KeywordsPropellantIsothermal processCalorimeter (particle physics)Thermal decompositionMelting pointDecompositionAnalytical Chemistry (journal)ChemistryThermal stabilityKeroseneMaterials scienceChromatographyThermodynamicsOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Ammonium dinitramide (ADN), NH 4 N(NO 2 ) 2 is being considered as one of the potential new energetic oxidizers for composite propellants. In this study, ADN crystals, prills and two ADN‐based propellants having different relative amounts of ingredients were characterized. The concentration of the crystals and the prills samples was determined using ion chromatography. The thermal behavior of the crystals, prills and propellants was studied using DSC, simultaneous TG‐DTA‐FTIR‐MS, ARC (accelerating rate calorimeter), HFC (heat flux calorimeter) and INC (isothermal nanocalorimeter). Decomposition of ADN was observed from all of the samples at temperatures above the melting point of ADN (~ 92 °C). Formation of N 2 O, NO 2 , H 2 O, CO 2 , CO, N 2 and NO was detected during the ADN decomposition. The thermal stability of the ADN samples at temperatures below the melting point of ADN was studied. Early solid decomposition of ADN, which generates N 2 O and H 2 O, was observed at 60 °C. Electrostatic discharge (ESD) and impact sensitivity of the ADN samples were determined. The crystals and prills are sensitive to impact, while the two propellants are relatively less ESD and impact sensitive.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.033
Threshold uncertainty score0.606

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.180
Teacher spread0.171 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it