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Record W2138713649 · doi:10.1007/s11746-006-1023-3

Variables Affecting the Production of Standard Biodiesel

2007· article· en· W2138713649 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of the American Oil Chemists Society · 2007
Typearticle
Languageen
FieldEngineering
TopicBiodiesel Production and Applications
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsBiodieselSodium methoxideSodium hydroxideChemistryBiodiesel productionMethanolCatalysisPotassium hydroxideOrganic chemistryAcid valueAlcoholGlycerolSodiumVegetable oilFatty acid methyl esterYield (engineering)Sodium carbonateMaterials science

Abstract

fetched live from OpenAlex

Abstract Biodiesel is composed of fatty acid methyl esters, currently made from vegetable oils using basic catalysts. The oils must be reacted two or three times with methanol, in the presence of sodium methoxide to make products which meet the ASTM and European biodiesel standards. It is also believed that sodium hydroxide can never be used as the catalyst because it causes soap formation, which either lowers the yield or raises the acid number and makes product isolation difficult. Methods for producing standard biodiesel from low‐acid‐number soybean oil, in one chemical reaction using sodium hydroxide and a cosolvent, were recently reported. This study reports the effects of variables on the acid numbers and chemically bound glycerol contents of the products which led to the methods. These variables were the molar ratio of alcohol to oil, catalyst concentration, cosolvent volume, and reaction time. The alcohol‐to‐oil molar ratio must be at least 14, and the sodium hydroxide concentration should be at least 1.2 wt% (based on oil), to meet the necessary acid number and glycerol contents of the biodiesel. The volume of tetrahydrofuran cosolvent used must be 90–130% of that required to just create complete miscibility at the beginning of the reactions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.046
Threshold uncertainty score0.205

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.234
Teacher spread0.226 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it