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Record W2140381418 · doi:10.1002/qua.560050831

Interatomic forces over a wide range of nuclear separations

2009· article· en· W2140381418 on OpenAlexaff
G G Robinson, N. H. March, R. C. Perrin

Bibliographic record

VenueInternational Journal of Quantum Chemistry · 2009
Typearticle
Languageen
FieldPhysics and Astronomy
TopicQuantum, superfluid, helium dynamics
Canadian institutionsAtomic Energy (Canada)
Fundersnot available
KeywordsBohr modelvan der Waals forceBohr radiusPotential energyAtomic physicsVirial coefficientAtom (system on chip)Interatomic potentialScatteringChemistryLennard-Jones potentialPair potentialRADIUSRange (aeronautics)Virial theoremVan der Waals radiusPhysicsMolecular dynamicsMoleculeQuantum mechanicsMaterials science

Abstract

fetched live from OpenAlex

An interaction potential energy between rare gas atoms is set up which: (1) Reproduces the correct angular distribution for atomic scattering at high energies. (2) Fits the second virial coefficient and molecular orbital calculations at the smallest separations yet considered. (3) Fits the quantum mechanically calculated van der Waals constant. The most careful calculations we report are for Ne-Ne interactions. The gas scattering data in the high energy regime (25-100 kev) is shown to be fitted, to within experimental error, by either the Bohr or the Firsov potentials. This analysis gives information on the potential inside half a Bohr radius a0. The smallest distance at which molecular orbital calculations are available for Ne-Ne, on the other hand, is 2.5a0. A potential constructed by joining together forms appropriate for small and large nuclear separations is then used in molecular dynamical calculations of the liquid structure factor. The main features can be satisfactorily reproduced by a potential resembling a Lennard-Jones potential in the bowl, but joining on to a much softer potential at small distances. Finally, some remarks are made on the change in the two-body potential at large distances, in condensed matter, from that between rare gas atoms in a vacuum and the major differences for metal atom (eg. Li) interactions are stressed.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.400
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.266
Teacher spread0.261 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2009
Admission routes1
Has abstractyes

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