Controlled assembly of gold and silver nanoparticles using thermotropic amphiphilic and conventional liquid crystals
Bibliographic record
Abstract
The optical and thermal properties of liquid crystalline (LC) nanocomposites, amphiphilic or conventional rod-like liquid crystals with suspended thiolate-protected metal nanoparticles, have been studied. Three different types of liquid crystals have been used, namely amphiphilic, bolaamphiphilic as well as conventional rod-like liquid crystals. Dispersion of thiolate-protected gold and silver nanoparticles produces LC nanocomposites with either increased (hydrophilic particles) or decreased LC phase stability with increasing particle content. Based on these observations we predict several structural models for the organizations of the immersed particles within the organized, yet fluid liquid crystalline supramolecular assemblies arising from microphase segregation effects of incompatible structural sub-units.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".