Chemical composition and microstructure of waxy plant surfaces: triterpenoids and fatty acid derivatives on leaves of <i>Kalanchoe daigremontiana</i>
Why this work is in the frame
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Bibliographic record
Abstract
Abstract The vast surfaces of plant leaves are protected by a coating of cuticular waxes. While the bulk composition of wax mixtures from various plant species has been reported, chemical information on the outermost leaf surface is lacking to date. The goal of the present study was to explore the use of ToF‐SIMS for surface analyses of plant leaves of the species Kalanchoe daigremontiana . It was found that the two major wax triterpenoids, glutinol and friedelin, were both present at the lower leaf surface in high concentrations. In contrast, the predominant wax alkane, tritriacontane, was not detectable by ToF‐SIMS. Three other unidentified compounds that had not been detected in the bulk wax mixture were present at the surface, further demonstrating that the outermost layer of molecules differed drastically in composition from the underlying wax mixture. Mapping experiments showed that all compounds were distributed fairly homogenously across the lower leaf surface, exhibiting no apparent gradients across epidermal cells and within the surface area of individual cells Copyright © 2010 John Wiley & Sons, Ltd.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it