Synthesis of Double Side-Chain Liquid Crystalline Block Copolymers Using RAFT Polymerization and the Orientational Cooperative Effect
Bibliographic record
Abstract
We report on the synthesis and characterization of a new type of diblock copolymer that is composed of two side-chain liquid crystalline polymers (SCLCP1- block -SCLCP2). The diblock copolymer of poly{6-[4-(4-methoxyphenylazo)phenoxy]hexyl methacrylate}- block -poly{6-[4-(4-cyanophenyl)phenoxy]hexyl methacrylate} (PAzoMA- b -PBiPMA) was successfully synthesized using the reversible addition−fragmentation chain transfer (RAFT) polymerization. Low-polydispersity samples of various compositions can be prepared using either PAzoMA or PBiPMA macromolecular chain transfer agent. We show that the orientational cooperative effect can be effective even in microphase-separated samples due to the interaction of the two mesogens via the interface. Indeed, the photoinduced orientation of azobenzene groups on the PAzoMA block can bring biphenyl groups on the PBiPMA block to orient in the same direction inside their respective lamellar domains. While RAFT can be used to access to double or all-SCLC block copolymers, this study also demonstrates the potential interest of exploring the interplay of the LC order of different SCLCPs within a microphase-separated system.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".