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Record W2161092852 · doi:10.1139/s08-045

The fate of natural organic matter during UV/H<sub>2</sub>O<sub>2</sub> advanced oxidation of drinking waterA paper submitted to the Journal of Environmental Engineering and Science.

2009· article· en· W2161092852 on OpenAlexafffundvenue
Siva Sarathy, Madjid Mohseni

Bibliographic record

VenueCanadian Journal of Civil Engineering · 2009
Typearticle
Languageen
FieldEnvironmental Science
TopicAdvanced oxidation water treatment
Canadian institutionsUniversity of British Columbia
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsChemistryBiodegradationOrganic matterDichloroacetic acidAcetaldehydeWater treatmentFormaldehydeUltravioletSurface waterEnvironmental chemistryDegradation (telecommunications)Natural organic matterHydrogen peroxideHumic acidOrganic chemistryMaterials scienceEnvironmental engineeringEthanol

Abstract

fetched live from OpenAlex

At conditions within the range of those typically applied for commercial drinking water applications, the impact of ultraviolet and hydrogen peroxide (UV/H 2 O 2 ) advanced oxidation (AO) on the concentration, spectral characteristics, hydrophobicity, and biodegradability of natural organic matter (NOM) in a raw surface water and ultrafiltered surface water was studied. At an initial H 2 O 2 dose of 20 mg L –1 , UV/H 2 O 2 mineralized less than 15% of the NOM in raw surface water at a fluence of 1500 mJ cm –2 . Natural organic matter in ultrafiltered surface water was mineralized by at least 27% after about 1500 mJ cm –2 . Partial oxidation of NOM led to ring opening of aromatic structures, cleavage of conjugated double bonded carbon structures, and reduction in the degree of aromatic substitution. The UV/H 2 O 2 AO preferentially reacted with hydrophobic fractions of NOM leading to the formation of hydrophilic products. The treatment oxidized recalcitrant NOM into more readily biodegradable compounds with significant increases in formaldehyde and acetaldehyde concentrations. Depending on NOM properties for a given water, UV/H 2 O 2 AO may cause partial oxidation of NOM leading to the formation of biodegradable compounds. The presence of these species may need to be addressed with a downstream process capable of improving biological stability.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.238
Threshold uncertainty score0.652

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.002
GPT teacher head0.152
Teacher spread0.151 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations49
Published2009
Admission routes3
Has abstractyes

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