Factors limiting oxygen delignification of kraft pulp
Bibliographic record
Abstract
Softwood kraft pulp was subjected to a laboratory one- and three-stage oxygen delignification process. Pulp and liquor samples were collected at different stages of the process with particular attention being paid to the early and late stages. A novel residual lignin isolation method extracted about 65% of the oxidized residual lignins at a purity exceeding 90%. Using this methodology coupled to quantitative 31 P NMR, 13 C NMR, 2D heteronuclear (HMQC) NMR spectroscopic and analytical pyrolysis techniques allowed a thorough characterization of the residual and solubilized lignin fractions at the various stages of the process. Our conclusions do not point to a single factor as being responsible for the limits confronting oxygen delignification. Amongst the major factors impeding the effectiveness of oxygen delignification are: (i) the accumulation of relatively inert 5,5' biphenyl structures originally present in kraft lignin from dibenzodioxocin ring opening reactions; and (ii) the accumulation of considerably less reactive p-hydroxyphenyl structures. Detailed quantitative information was obtained and discussed in relation to the presence and role of these unreactive phenolic fractions on the residual oxidized lignins. As such we arrived at important conclusions as to why and how these structures remain and accumulate on the fiber. In addition, issues related to the profiles of the total phenolic hydroxyl content of the residual lignins and the remaining arylglycerol β-O-4 structures are discussed.Key words: analytical pyrolysis, biphenyl structures, HMQC, NMR, oxidation mechanism, oxygen delignification, p-hydroxyphenyl moieties, quantitative 13 C NMR, quantitative 31 P NMR, residual lignin, solubilized lignin, total phenolic hydroxyls.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".