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Record W2166254616 · doi:10.3139/217.2601

Annular Extrudate Swell of a Fluoropolymer Melt

2012· article· en· W2166254616 on OpenAlex
Evan Mitsoulis, Savvas G. Hatzikiriakos

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueInternational Polymer Processing · 2012
Typearticle
Languageen
FieldChemical Engineering
TopicRheology and Fluid Dynamics Studies
Canadian institutionsUniversity of British Columbia
FundersNatural Sciences and Engineering Research Council of CanadaNational Technical University of Athens
KeywordsDie swellMaterials scienceViscoelasticityRheologySwellComposite materialSwellingSlip (aerodynamics)ExtrusionFluoropolymerShear rateCompressibilityMechanicsThermodynamicsPolymer

Abstract

fetched live from OpenAlex

Abstract Annular extrudate swell is studied for a fluoropolymer (FEP) melt using a tubular die. The rheological data of the melt have been fitted using (i) a viscous model (Cross) and (ii) a viscoelastic one (the Kaye – Bernstein, Kearsley, Zapas/Papanastasiou, Scriven, Macosko or K-BKZ/PSM model). Numerical simulations have been undertaken to study the extrudate swell of the FEP melt in an annular die. Compressibility, thermal and pressure effects on viscosity, and slip at the wall were taken into account. In all cases, slip at the wall is the dominant contribution reducing the swelling when compared with corresponding no-slip simulations. The viscous (Cross) simulations show that the swell decreases with increasing apparent shear rate, which is opposite to what happens in the extrusion of viscoelastic melts. On the other hand, the viscoelastic (K-BKZ) simulations correctly obtain increasing swelling with increasing shear (flow) rates. It was found that due to the mild viscoelasticity of FEP and its severe slip at the wall the swelling of this melt is relatively small, reaching values of about 20% for a wide range of apparent shear rates, exceeding 5000 s −1 . This is corroborated by experimental observations.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.462
Threshold uncertainty score0.489

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.259
Teacher spread0.248 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it