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Record W2169338718 · doi:10.1002/star.201200079

Influence of di‐functional versus multi‐functional chain extenders on the foamability of a potato starch‐based biopolymer

2012· article· en· W2169338718 on OpenAlexaff
Hitesh Oza, Michael R. Thompson, Andrew N. Hrymak, Qiang Liu

Bibliographic record

VenueStarch - Stärke · 2012
Typearticle
Languageen
FieldMaterials Science
Topicbiodegradable polymer synthesis and properties
Canadian institutionsAgriculture and Agri-Food CanadaWestern UniversityMcMaster University
Fundersnot available
KeywordsRheologyBiopolymerMaterials scienceStarchChemical engineeringPolylactic acidPolymerComposite materialChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract This study examines the effectiveness of di‐functional versus multi‐functional glycidyl ether chain extenders (CE) for improving the foamability of a commercial blend of hydrolyzed potato starch and polylactic acid, Solanyl® 30R (Solanyl Biopolymers Inc.). The blend was reactively modified in bulk using CEs at concentrations ranging from 0.5–2.5 wt% within a twin‐screw extruder operating at 170°C and 150 RPM. Thermal and rheological analysis of the modified blends found that only one multi‐functional polymeric CE was effective for altering the molecular structure of the blend while both significantly improved the foamability of the material. The two di‐functional CEs did not produce detectable changes in melt elasticity for the blend but again had a notable influence on improved foamability. Foamability was evaluated based on improvements to the material that increased foam stability (i.e. higher cell densities and smaller bubbles), and the results in this study suggested that these CEs influenced bubble expansion in ways other than simply causing rheological change.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.063
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.080
GPT teacher head0.272
Teacher spread0.192 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2012
Admission routes1
Has abstractyes

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