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Record W2183013271 · doi:10.1016/s0967-0653(98)85016-3

10.1016/s0967-0653(98)85016-3

2000· article· en· W2183013271 on OpenAlexvenueno aff

Bibliographic record

VenueTime to knit · 2000
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeochemistry and Elemental Analysis
Canadian institutionsnot available
Fundersnot available
KeywordsHydrothermal circulationGeologyBasaltGeochemistryPyriteChloriteSeawaterMineralogyOceanic crustQuartzPlagioclaseSubductionPaleontology

Abstract

fetched live from OpenAlex

Major, trace, and rare earth element (REE) analyses of 57 samples of altered and relatively fresh basalts from four different areas on the active Trans-Atlantic Geotraverse (TAG) hydrothermal mound have been completed to determine the geochemistry of alteration of the shallow oceanic crust beneath the mound and to calculate the magnitudes and directions of elemental exchanges between seawater and the oceanic crust during each step of the alteration sequence. Early high-temperature water-rock reactions resulted in the initial conversion of fresh basalt to chlorite ± quartz ± pyrite by reactions between basalt and a hydrothermal fluid‐seawater mixture. Fluid-rock reactions resulted in uptake of Al, Fe, Mg, H2O + , S, V, and Co. In addition, essentially all of the Ca, Na, and Sr were lost from the rock during alteration of plagioclase. The trace metals Cu, Ni, and Zn were leached from the rock, with almost all of the Cu being removed. Changes in Si were variable in direction and in general quite small. This was followed by replacement of the chlorite-rich assemblage by paragonite ± quartz ± pyrite during reactions with a hydrothermal fluid enriched in alkalis. This resulted in additional uptake of Si, Fe, S, and Co, as well as small amounts of Na, K, Sr, Ba, and Zn. Other components were lost from the rock, including Mg, H 2O + , and V, and small amounts of Al. Further silicification of the paragonite-rich assemblage resulted in continuing and complete loss of Mg and H2O + , and almost complete loss of V. This stage of the alteration sequence is also responsible for the largest increases in the Si, Fe, S, and Co contents of the altered rocks, some of which show gains in Cu and Zn, presumably in association with the sulfides. Chloritization within basalts from the edges of the mound attests to reactions between hydrothermal fluids and rocks at high temperatures extending in the subsurface at least to the periphery of the mound. Distinct geochemical and mineralogical differences during alteration on different parts of the mound are indicative of fluids with varying proportions of hydrothermal fluid s and seawater.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.798
Threshold uncertainty score0.380

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)1.0001.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.149
Teacher spread0.144 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations42
Published2000
Admission routes1
Has abstractyes

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