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Record W2256493273 · doi:10.1021/acssuschemeng.5b01772

Green Biocomposites from Nanoengineered Hybrid Natural Fiber and Biopolymer

2016· article· en· W2256493273 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueACS Sustainable Chemistry & Engineering · 2016
Typearticle
Languageen
FieldEngineering
TopicDyeing and Modifying Textile Fibers
Canadian institutionsUniversity of Alberta
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsMaterials scienceBiocompositeFiberFourier transform infrared spectroscopyChemical engineeringExfoliation jointScanning electron microscopeComposite materialThermal stabilityComposite numberNanotechnologyGraphene

Abstract

fetched live from OpenAlex

The surface grafting of polyhedral oligomeric silsesquioxanes (POSS) nanocages onto keratin biofiber and development of hybrid keratin fiber by dissolution of feather keratin, exfoliation/intercalation of nanoclay in the keratin matrix and regeneration into fiber are reported, respectively. The graft polymerization of POSS on to the surface of keratin fibers was observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), and confirmed with X-ray photoelectron spectroscopy (XPS). The presence and dispersion of nanoclay, in in situ reinforced and regenerated fiber, was investigated and confirmed by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and TEM. The nanomodifications resulted in substantial improvements in the properties of all modified fibers including enhanced thermal stability and reduced moisture uptake compared to unmodified native fibers. The native and modified fibers were further blended with copolymer matrix of 30% styrene with 2-(acryloyloxy) ethyl stearate to prepare the biocomposite films. The properties of the resultant biocomposites were investigated using dynamic mechanical analysis (DMA), flame tests, and SEM. The investigations demonstrated improvements in storage moduli, fiber–matrix adhesion, and reductions in flammability of modified fiber reinforced biocomposites as compared to the neat fiber reinforced biocomposites.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.039
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.002
GPT teacher head0.157
Teacher spread0.155 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it