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Characterization of Plasmodium falciparum Holo‐ACP Synthase: a Potential Antimalarial Drug Target

2011· article· en· W2282899861 on OpenAlexafffund
Germaine Tami, Peter Murphy, David M. Byers

Bibliographic record

VenueThe FASEB Journal · 2011
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicChemical Synthesis and Analysis
Canadian institutionsDalhousie University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsApicoplastPlasmodium falciparumAcyl carrier proteinEnzymeBiologyBiochemistryCoenzyme ASignal peptideATP synthasePeptide sequenceBiosynthesisMalariaApicomplexaGeneReductase

Abstract

fetched live from OpenAlex

The protozoan parasite Plasmodium falciparum is responsible for the most lethal form of malaria and kills about one million people annually, most of whom are children in sub‐Saharan Africa. Fatty acid synthesis (FAS) is a validated antimalarial strategy: it occurs in a specialized parasite organelle (the apicoplast) and uses a dissociated type II FAS system similar to bacteria. Bioinformatics analysis indicates that P. falciparum encodes a single enzyme, holo‐ACP synthase ( Pf AcpS), responsible for activating acyl carrier protein (ACP) involved in FAS. Pf AcpS consists of a signal/leader peptide, a large N‐terminal domain of unknown function, and a C‐terminal domain (PfAcpS‐C) that is highly homologous (30–50% similarity) to trimeric bacterial AcpS enzymes. We have expressed and isolated the soluble Pf AcpS‐C domain and shown that it catalyzes the transfer of (acyl)phosphopantetheine to Pf ACP from coenzyme A or from its derivatives acetyl‐CoA and octanoyl CoA. Pf AcpS exhibited much lower activity than E. coli AcpS and preferred higher concentrations of CoA derivatives. Several novel inhibitors of E. coli AcpS also blocked Pf AcpS activity, although the degree of inhibition differed between the enzymes. The sequence similarity between Pf AcpS‐C and bacterial AcpS enzymes suggests that drugs targeting the latter might also inhibit P. falciparum growth and pathogenesis. (Supported by NSERC)

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.209
Teacher spread0.199 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2011
Admission routes2
Has abstractyes

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