Phosphaalkene-oxazoline copolymers with styrene as chiral ligands for rhodium(<scp>i</scp>)
Bibliographic record
Abstract
The radical-initiated copolymerization of phosphaalkene-oxazoline, MesP[double bond, length as m-dash]C(Ph)CMe2Ox [1, Ox = CNOCH(iPr)CH2] with different loadings of styrene affords poly(methylenephosphine-co-styrene)s [2a (1 : S = 1 : 2): Mw = 7400 g mol(-1), PDI = 1.1; 2b (1 : S = 1 : 5): Mw = 18 000 g mol(-1), PDI = 1.2; 2c (1 : S = 1 : 10): Mw = 16 000 g mol(-1), PDI = 1.3]. Copolymers 2a-2c are demonstrated as viable macromolecular ligands for rhodium(i). By comparison with the crystallographically characterized model P,N-bidentate complex, [Mes(Me)P-CH(Ph)CMe2Ox·Rh(cod)]BF4, the polymer complexes [2·Rh(cod)]BF4 were prepared. The macromolecular metal complexes were characterized by GPC {for [2a·Rh(cod)]BF4: Mw = 14 000 g mol(-1), PDI = 1.2}, UV/Vis spectroscopy, (1)H, (13)C and (31)P NMR spectroscopy. Integration of the (31)P NMR spectra of mixtures of 2 and [Rh(cod)2]BF4 permitted the determination of the mol% of incorporation of monomer 1 in copolymer 2 (2a: 17%; 2b: 5%; 2c: 4%). These results compared favorably with those determined by elemental analysis (2a: 17%; 2b: 6%).
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.011 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".