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Record W2299475445 · doi:10.2136/vzj2015.01.0014

Electrical Conductivity Breakthrough Experiment and Immobile Water Estimation in Organic Substrates: Is <i>R</i> = 1 a Realistic Assumption?

2015· article· en· W2299475445 on OpenAlexaff
Jean Caron, Guillaume Létourneau, J. André Fortin

Bibliographic record

VenueVadose Zone Journal · 2015
Typearticle
Languageen
FieldEnvironmental Science
TopicGroundwater flow and contamination studies
Canadian institutionsUniversité Laval
Fundersnot available
KeywordsSorptionPeatTRACERChemistryDistilled waterSoil waterSoil scienceSawdustEnvironmental chemistryElectrical resistivity and conductivityAdsorptionChromatographyEnvironmental scienceOrganic chemistryPhysics

Abstract

fetched live from OpenAlex

Core Ideas Breakthrough of NaCl in peat shows that R may differ from 1. Immobile water in peat is difficult to estimate because of NaCl sorption. Solute sorption in peat varies because of uncoiling of organic components. Measuring electrical conductivity (EC) in outflow breakthrough curves (BTCs) is an approach commonly used to define transport parameters because it is rapid, inexpensive, and reliable. Earlier work has raised questions regarding the assumption that the retardation factor may be set at R = 1 when using EC as a tracer in organic soils. This study investigates the breakthrough of a NaCl tracer in a peat–sawdust mixture leached with distilled water. The results show that in such system, R may significantly differ from 1 because of sorption of Na + and Cl − by peat with the R value estimated by batch experiments to reach 1.9 for Na + and 1.5 for Cl − . The sorption properties may vary during solute transport because of uncoiling of humic and fulvic components with decreasing ionic strength of the solution.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.424
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.262
Teacher spread0.238 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations13
Published2015
Admission routes1
Has abstractyes

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