<sup>2</sup>H double- and zero-quantum filtered NMR spectroscopy for probing the environments of water in Nafion
Bibliographic record
Abstract
Multiple quantum 2H NMR spectroscopy is used to study the structure and dynamics of D2O in Nafion membranes as a function of membrane hydration. By employing both double- and zero-quantum filtered experiments, residual quadrupolar coupling constants and T2 relaxation values are obtained. The residual couplings vary from 240 to 20 Hz and the T2 values range from 20 to 180 ms, with the high hydration values having smaller couplings and longer T2 values. Analysis of the data using a water-exchange model suggests that the changes in parameters arise from a change in the fraction of time water spends in the anisotropic environments and not from changes in the order parameters that characterize the anisotropic sites. It has been found that a two-site model is needed to accurately fit the spectra above a hydration level of 10 D2O per sulfonate, with the second site having a negligible residual quadrupolar coupling. The data supports a model with two different hydration layers at high hydration and can be understood in terms of the recently proposed parallel-channel model for Nafion hydration.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".