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Record W2313281865 · doi:10.1021/la200596c

A General Poisson−Boltzmann Model with Position-Dependent Dielectric Permittivity for Electric Double Layer Analysis

2011· article· en· W2313281865 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueLangmuir · 2011
Typearticle
Languageen
FieldChemistry
TopicElectrostatics and Colloid Interactions
Canadian institutionsLaurentian University
Fundersnot available
KeywordsPermittivityRelative permittivityBoltzmann constantDielectricMaterials scienceLayer (electronics)Poisson distributionPosition (finance)Condensed matter physicsDielectric permittivityChemistryMolecular physicsComputational physicsPhysicsThermodynamicsComposite materialOptoelectronicsMathematics

Abstract

fetched live from OpenAlex

In this paper, we propose a general Poisson-Boltzmann model for electric double layer (EDL) analysis with the position dependence of dielectric permittivity considered. This model provides physically reasonable property profiles in the EDL region, and it is then utilized to investigate the depletion layer effect on EDL structure and interaction near hydrophobic surfaces. Our results show that both the electric potential and the interaction pressure between surfaces decrease due to the lower permittivity in the depletion layer. The reduction becomes more profound at larger variation magnitude and range. This trend is in general agreement with that observed from the previous stepwise model; however, that model has overestimated the influence of permittivity variation effect. For the thin depletion layer and the relative thick EDL, our calculation indicates that the permittivity variation effect on EDL usually can be neglected. Furthermore, our model can be readily extended to study the permittivity variation in EDL due to ion accumulation and hydration in the EDL region.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.405
Threshold uncertainty score0.658

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.260
Teacher spread0.236 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it