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Record W2319267224 · doi:10.1021/je300482b

Vapor–Liquid Phase Equilibria and Physical Properties Measurements for Ternary Systems (Methane + Decane + Hexadecane)

2012· article· en· W2319267224 on OpenAlexaff
Mohammad Kariznovi, Hossein Nourozieh, Jalal Abedi

Bibliographic record

VenueJournal of Chemical & Engineering Data · 2012
Typearticle
Languageen
FieldEngineering
TopicPhase Equilibria and Thermodynamics
Canadian institutionsUniversity of Calgary
Fundersnot available
KeywordsChemistryTernary operationThermodynamicsDecaneMethaneEquation of stateTernary numeral systemHexadecaneBinary systemPhase (matter)SolubilityBinary numberOrganic chemistry

Abstract

fetched live from OpenAlex

The vapor–liquid equilibrium (VLE) data for ternary systems (methane + decane + hexadecane) have been determined using a designed pressure–volume–temperature (PVT) apparatus. Three different (decane + hexadecane) binary mixtures were prepared, and the solubility and phase equilibria of three prepared mixtures with methane at ambient temperature and different pressures from (1 to 8) MPa were studied. The phase composition and saturated liquid density and viscosity were reported for each pressure. The VLE data of the ternary mixtures were correlated using Soave–Redlich–Kwong and Peng–Robinson equations of state. The equations of state models with their best-fitted parameters of the binary systems, (methane + decane and methane + hexadecane), were used to predict the VLE data of ternary systems. Both equations of state were found to be capable of describing the phase equilibria of binary pairs and ternary systems over the range of studied conditions. The Peng–Robinson equation of state gave better predictions of saturated liquid densities than those of the Soave–Redlich–Kwong equation of state.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.696
Threshold uncertainty score0.875

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.074
GPT teacher head0.286
Teacher spread0.212 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations10
Published2012
Admission routes1
Has abstractyes

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