Temperature-dependent reorientation dynamics of laser dyes in alkane and alcohol solvents
Bibliographic record
Abstract
The rotational dynamics of similar sized coumarin 6 (C6), coumarin 7 (C7), and coumarin 30 (C30) laser dyes has been studied in alkane and alcohol solvents using steady-state and time-resolved fluorescence depolarization methods. The estimated rotational reorientation times of these probes are observed to vary linearly as a function of viscosity over the range of temperatures studied. It is found that the rotational reorientation time measurements of these molecules in alcohol and alkane typically have relaxation times on the order of picoseconds. The rotational reorientation times of the C7 molecule are greater than those of the C6 and C30 molecules. It was observed that C7 rotates faster in both the solvents than C6 and C30, indicating that the effects of the medium and structural differences of molecules lead to slower rotation.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".