Hydrotreating of Heavy Gas Oil on Mesoporous Mixed Metal Oxides (M–Al<sub>2</sub>O<sub>3</sub>, M = TiO<sub>2</sub>, ZrO<sub>2</sub>, SnO<sub>2</sub>) Supported NiMo Catalysts: Influence of Surface Acidity
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Bibliographic record
Abstract
Mesoporous mixed metal oxides, TiO 2 –Al 2 O 3, ZrO 2 –Al 2 O 3, and SnO 2 –Al 2 O 3, were synthesized using a novel method and were used as a support material for the NiMo hydrotreating catalyst. The catalyst was prepared via the incipient wetness sequential impregnation method. All catalysts were characterized using N 2 adsorption–desorption isotherms (BET), X-ray diffraction, FTIR, pyridine-FTIR, acridine-FTIR, CO-chemisorption, ICP-MS, TPD, and TPR. The HDS and HDN activities of the catalysts were determined using Athabasca bitumen derived heavy gas oil at industrial reaction conditions. The catalytic activity of synthesized NiMo/γ-Al 2 O 3 catalyst was also determined for comparative studies. Low angle XRD and BET analysis has confirmed that the method developed for synthesis is suitable for the preparation of a mesoporous mixed oxide based NiMo hydrotreating catalyst. H 2 -TPR analysis has confirmed that the introduction of metal oxides such as ZrO 2, TiO 2, and SnO 2 in alumina increases the active metal (Mo) and support (alumina) interactions. The highest reduction temperature is observed in the SnO 2 containing catalyst. NH 3 -TPD has confirmed the increase in acidic strength of catalysts after introduction of metal oxides, and it follows the order NiMo/SnO 2 –Al 2 O 3 > NiMo/ZrO 2 –Al 2 O 3 > NiMo/TiO 2 –Al 2 O 3 . It was observed from acridine-FTIR analysis that the catalysts having strong acidic strength hold acridine strongly at high temperatures. This implies that catalysts with higher acidity are prone to inhibition by nitrogen containing compounds present in feed, and it will affect the catalytic activity. The HDS and HDN activities follow the order NiMo/TiO 2 –Al 2 O 3 > NiMo/mesoAl 2 O 3 (mesoporous) > NiMo/ZrO 2 –Al 2 O 3 > NiMo/γ-Al 2 O 3 > NiMo/SnO 2 –Al 2 O 3 . The higher activity of the NiMo/TiO 2 –Al 2 O 3 catalyst is due to higher metal dispersion as observed from CO-chemisorption and a moderate increase in acidic strength. Therefore, increasing the acidity of alumina support to much higher levels by incorporating metal oxides having strong Lewis acidity would not help in enhancing HDN and HDS activity for nitrogen rich feeds, such as Athabasca bitumen derived heavy gas oil due to inhibition effects.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.005 | 0.004 |
| Meta-epidemiology (narrow) | 0.002 | 0.003 |
| Meta-epidemiology (broad) | 0.004 | 0.001 |
| Bibliometrics | 0.001 | 0.005 |
| Science and technology studies | 0.001 | 0.001 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.002 | 0.001 |
| Research integrity | 0.002 | 0.004 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
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Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it