Oxidation of a Dimethylplatinum(II) Complex with Oxaziridines: A Hemiaminal Intermediate but No Oxo Complex
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Bibliographic record
Abstract
The complex [PtMe 2 (bipy)] ( 1; bipy = 2,2′-bipyridine) fails to react with the oxaziridine derivatives RCHON- t -Bu (R = H, Ph, 2-pyridyl) in acetone at room temperature, but an easy reaction occurs in methanol solution to give the platinum(IV) complex [Pt(OH)(OMe)Me 2 (bipy)] and the corresponding imine RCH═N- t -Bu. In the case with R = Ph, the hemiaminal intermediate [Pt(OMe)(OCHPhNH- t -Bu)Me 2 (bipy)] was formed and then reacted only slowly to form [Pt(OH)(OMe)Me 2 (bipy)] and PhCH═N- t -Bu. Computational studies indicate that the reaction of 1 with oxaziridines occurs to give a charge transfer complex but that further reaction requires assistance from hydrogen bonding and coordination with specific methanol molecules. The work provides strong support for the theory that oxygen atom transfer to 1 from either dioxiranes or oxaziridines must be coupled to proton transfer and does not involve oxoplatinum(IV) intermediates.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.076 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it