Neutron Diffraction Characterization of C–H···Li Interactions in a Lithium Aluminate Polymer
Bibliographic record
Abstract
The reaction of AlMe 3 with t BuLi in the presence of trimethylacetonitrile affords the bimetallic complex [ t Bu(Me)Al(μ-Me) 2 Li·NC( t Bu)] ∞ ( 1 ). Pseudotetrahedral Al centers form by the nucelophilic addition of t BuLi to AlMe 3 .The alkali-metal center is stabilized through coordination of the unreacted nitrile and polymer formation via the construction of Al(μ-Me) n Li ( n = 1, 2) motifs. Neutron diffraction evidences agostic interactions in the bridging methyl group to give further stabilization. There is only one previous report of a neutron structure of a lithium aluminate compound. This work therefore offers an important structural example of agostic interactions and the precise nature of Al(μ-Me) 2 Li bridging.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".