Three-Phase Equilibrium Conditions of TiAAB Semiclathrates Formed from N<sub>2</sub>, CO<sub>2</sub>, and Their Mixtures
Bibliographic record
Abstract
A variable-volume reactor was used for measuring the solid–vapor–liquid equilibrium conditions of semiclathrates formed in an aqueous solution of tetra-iso-amyl ammonium bromide (TiAAB). The TiAAB semiclathrates were formed from pure CO 2, pure N 2, and three mixtures of CO 2 (1) + N 2 (2), which had cylinder compositions of x 1 = 0.78, x 1 = 0.52, and x 1 = 0.21. The experimental temperatures ranged from (302 to 307) K, the experimental pressures ranged from (220 to 2115) kPa, and the concentration of TiAAB in solution was constant at a mass fraction of w TiAAB = 0.1403. For all of the gases used in the present study, it was found that, at a given pressure, the minimum temperature required to form TiAAB semiclathrates is significantly higher than that required for forming both gas hydrates or tetrabutyl ammonium bromide (TBAB) semiclathrates from the same gases.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".