Porous Ultra-Capacitor Electrodes Fabricated by Solution Precursor Plasma Spray: Molybdenum Oxide vs. Molybdenum Nitride
Bibliographic record
Abstract
Abstract Solution precursor plasma spray has been shown capable of depositing high surface area transition metal oxide coatings of interest as ultra-capacitor electrodes. These materials exhibit mixed double layer and pseudo-capacitive properties, enabling larger charge storage capacity than electrical double layer capacitor electrodes such as carbon. This investigation explored potential of SPPS to deposit molybdenum oxide with microstructures suitable for use as pseudo-capacitive electrodes. It further identified a two-step temperature-programmed heat treatment that resulted in the topotactic phase transformation of the α-MoO3 deposits into high specific surface area molybdenum nitrides exhibiting a higher electrochemical stability window (i.e. a higher specific area capacitance). The electrochemical behavior of molybdenum oxide and molybdenum nitride deposits formed under different deposition conditions was studied using cyclic voltammetry in order to assess the influence of the resulting microstructure on the charge storage behavior and potential for use in ultra-capacitors.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.003 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".