MétaCan
Menu
Back to cohort
Record W2329260634 · doi:10.1055/s-0033-1339511

SYNFORM ISSUE 2013/09

2013· article· en· W2329260634 on OpenAlexaff
Matteo Zanda

Bibliographic record

VenueSynfacts · 2013
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicChemical Synthesis and Analysis
Canadian institutionsQueen's University
Fundersnot available
KeywordsChemistryEarth scienceGeology

Abstract

fetched live from OpenAlex

Following a glorious Saturday full of sunshine, this beautiful Scottish summer suddenly switched to a gloomy and rainy Sunday morning, which is the ideal situation for staying home and writing this editorial! Let's have a look at the articles in this new issue of SYNFORM then. The first SYNSTORY is about a novel catalytic enantioselective hydroacylation reaction developed by Vy Dong (USA) that converts -hydroxy-ketones into the corresponding enantiomerically pure -butyrolactones. The next SYNSTORY brings us to the realm of peptide chemistry, where Mark Distefano (USA) found an efficient solid-phase method for producing peptides having a C-terminal methyl ester. The third SYN- STORY takes us to the highly chemoselective synthesis of -aryl piperidines developed by Olivier Baudoin (France) which relies on the use of 2-phenyl-pyrrole phosphine ligand. The issue is completed by a report on a very interest ing novel use of Grignard reagents which, as demonstrated by Peter O'Brien (UK), can be used as chiral building blocks for the synthesis of stereopure 1,2-diols and rigid amines. I just had a look outside the window; it's still raining cats and dogs here...

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.317
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.210
Teacher spread0.206 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2013
Admission routes1
Has abstractyes

Explore more

Same venueSynfactsSame topicChemical Synthesis and AnalysisFrench-language works237,207