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Record W2329837031 · doi:10.1021/ie203025f

Mass Transfer at a Vertical Oscillating Screen Stack in Relation to Catalytic and Electrochemical Reactor Design

2012· article· en· W2329837031 on OpenAlexaff
M.H. Abdel‐Aziz, I. Nirdosh, G.H. Sedahmed

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2012
Typearticle
Languageen
FieldEngineering
TopicElectrodeposition and Electroless Coatings
Canadian institutionsLakehead University
Fundersnot available
KeywordsStack (abstract data type)Mass transferMass transfer coefficientLimiting currentElectrochemistryDiffusionChemistryAnalytical Chemistry (journal)Materials scienceMechanicsThermodynamicsElectrodeChromatographyPhysicsPhysical chemistry

Abstract

fetched live from OpenAlex

The aim of the present work is to improve the performance of the parallel plate catalytic and electrochemical reactor in conducting diffusion controlled reactions by using parallel oscillating vertical arrays of closely packed screens. To this end, rates of mass transfer at oscillating vertical single screen and arrays of closely packed screens were studied by measuring the limiting current of the cathodic deposition of copper from acidified copper sulfate. Variables studied were amplitude and frequency of vibration, screen mesh number, and number of screens per stack. The mass transfer data at a single vibrating screen were correlated by the equation: Sh = 0.73Sc 0.33 Re v 0.38 . Increasing mesh number of the screen was found to increase the mass transfer coefficient, while increasing the number of screens per stack decreased the mass transfer coefficient below single screen value. The enhancement ratio between oscillating screen array and oscillating vertical plate (the volumetric mass transfer coefficient ratio) ranged from 11.7 to 27.87 depending on the operating conditions. Electrical energy consumption of the present reactor was found to be lower than the value reported in the literature for electrowinning of copper using traditional parallel plate reactor. In view of this, the possibility of using oscillating vertical screen stack in building high space-time yield modular parallel plate electrochemical reactor suitable for wastewater treatment, electroorganic synthesis, and electrochemical energy storage via redox cells was noted. Also, the possibility of using the present geometry in building catalytic reactors suitable for conducting diffusion controlled liquid–solid reaction was highlighted.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.026
Threshold uncertainty score0.983

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.060
GPT teacher head0.284
Teacher spread0.225 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2012
Admission routes1
Has abstractyes

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