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Record W2333184462 · doi:10.1021/ef101097c

Investigation of Fouling Mechanisms of a Light Crude Oil Using an Alcor Hot Liquid Process Simulator

2010· article· en· W2333184462 on OpenAlexaff
Zhiming Fan, Parviz Rahimi, Ryan McGee, Qing Wen, Teclemariam Alem

Bibliographic record

VenueEnergy & Fuels · 2010
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsNatural Resources Canada
Fundersnot available
KeywordsFoulingAsphalteneChemistryCrude oilLaminar flowChemical engineeringPetroleum engineeringMaterials scienceGeologyOrganic chemistryThermodynamics

Abstract

fetched live from OpenAlex

Fouling mechanisms of a light conventional crude were investigated by characterizing the crude oil, performing fouling tests using a bench-scale Alcor hot liquid process simulator (HLPS) unit and characterizing fouling deposits by means of elemental analysis, scanned electron microscopy (SEM), thermogravimetric analysis (TGA), and photoacoustic infrared spectroscopy (PAS-IR). In addition, a mathematical fouling model was developed under a laminar flow regime following Epstein’s methodology. Fouling tests were conducted at different temperatures and bulk velocities. Although the asphaltene content in the crude oil is low, the asphaltenes are still unstable because of a high saturate content and this crude oil has a high fouling propensity. On the basis of the fouling test results, fouling model analysis, and characterization of fouling deposits, the fouling mechanism of this crude oil can be explained as follows: In a laminar flow regime, unstable asphaltenes transport to the hot surface, become attached to the surface, and then, through chemical reactions, form fouling deposits. Mass transfer of entrained suspended particulates in the crude oil also contributes to fouling, although it is not the main cause. However, under turbulent flow conditions, such as those that prevail in industrial operations, it is expected that suspended particles would play a greater role in fouling.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.009

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.257
Teacher spread0.239 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations38
Published2010
Admission routes1
Has abstractyes

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