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Record W2333849182 · doi:10.1002/ejic.201190075

Rare‐Earth Cobalt Gallides RE<sub>4</sub>Co<sub>3</sub>Ga<sub>16</sub> (RE = Gd–Er, Y): Self‐Interstitial Derivatives of RE<sub>2</sub>CoGa<sub>8</sub>A Tale of Two Polymorphs – Growth and Characterization of α‐LnNiGa<sub>4</sub> (Ln = Y, Gd–Yb) and β‐LnNi<sub>1–<i>x</i></sub>Ga<sub>4</sub> (Ln = Tb–Er)Solution Chemistry Synthesis of Intermetallic Gold–Lithium NanoparticlesMetal Anions in Metal‐Rich Compounds and Polar IntermetallicsRevisiting the Zintl–Klemm Concept: <i>A</i><sub>2</sub>AuBi (<i>A</i> = Li or Na)Crystal Structure and Properties of Yb<sub>5</sub>Ni<sub>4</sub>Ge<sub>10</sub>Magnetism in Giant Unit Cells – Crystal Structure and Magnetic Properties of R<sub>117</sub>Co<sub>52+<i>δ</i></sub>Sn<sub>112+<i>γ</i></sub> (R = Sm, Tb, Dy) (Eur. J. Inorg. Chem. 26/2011)

2011· article· en· W2333849182 on OpenAlexaff
Arthur Mar, Julia Y. Chan, Raymond E. Schaak, Myung‐Hwan Whangbo, Gordon J. Miller, Mercouri G. Kanatzidis, Michael Shatruk

Bibliographic record

VenueEuropean Journal of Inorganic Chemistry · 2011
Typearticle
Languageen
FieldPhysics and Astronomy
TopicRare-earth and actinide compounds
Canadian institutionsUniversity of Alberta
Fundersnot available
KeywordsIntermetallicChemistryCrystallographyCobaltAntibonding molecular orbitalTernary operationInorganic chemistryPhysicsAtomic orbitalElectron

Abstract

fetched live from OpenAlex

Abstract The front cover picture shows the clock tower, the “Campanile”, of Iowa State University where John Corbett did the ground‐breaking research in polar intermetallics that forms the basis of his Viewpoint in this cluster issue. Superimposed on this background are structures and data to visualize the broad scope of topic. The complexity of structure is displayed by the ternary rare‐earth cobalt gallides that contain interstitial atoms (top left, A. Mar et al.), a calcium‐poor intermetallic phase of the Ca/Ni/Ge system (top right from the lab of T. Fässler), and a single crystal of a polymorph of thallium nickel gallide (bottom right, J. Chan et al.). The potentially general synthesis of colloidal nanoparticles – Au 3 Li from the lab of R. E. Schaak – is outlined mid left. The groups of M. H. Whangbo and G. Miller devote their contributions to the theoretical aspects of bonding (depicted top centre, the plots showing Au–Au bonding and antibonding interactions in Dy 2 Au 2 In and mid right, the effects of ionic interactions on the structural properties of isoelectronic intermetallic compounds, respectively). Representative of the range of properties discussed is the magnetic susceptibility of Yb 5 Ni 4 Ge 10 (bottom left, M. G. Kanatzidis et al.). We thank the authors for the use of the graphics from their papers on the cover.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.005
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Scholarly communication, Research integrity
Consensus categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.010
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0050.002
Meta-epidemiology (narrow)0.0080.008
Meta-epidemiology (broad)0.0100.003
Bibliometrics0.0030.005
Science and technology studies0.0020.009
Scholarly communication0.0020.006
Open science0.0050.004
Research integrity0.0030.008
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.188
Teacher spread0.178 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2011
Admission routes1
Has abstractyes

Explore more

Same venueEuropean Journal of Inorganic ChemistrySame topicRare-earth and actinide compoundsFrench-language works237,207