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Record W2334747259 · doi:10.1021/jz3015327

Complex Wave Function Reconstruction and Direct Electromagnetic Field Determination from Time-Resolved Intensity Data

2012· article· en· W2334747259 on OpenAlexaff
Cian Menzel-Jones, Moshe Shapiro

Bibliographic record

VenueThe Journal of Physical Chemistry Letters · 2012
Typearticle
Languageen
FieldPhysics and Astronomy
TopicLaser-Matter Interactions and Applications
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsFourier transformExcitationPulse wavePhysicsPerturbation (astronomy)Wave functionFunction (biology)Electromagnetic fieldElectromagnetic pulseComputational physicsMathematical analysisOpticsMathematicsQuantum mechanicsLaser

Abstract

fetched live from OpenAlex

We present a reference-free robust method for the nondestructive imaging of complex time-evolving molecular wave functions using as input the time-resolved fluorescence signal. The method is based on expanding the evolving wave function in a set of bound stationary states and determining the set of complex expansion coefficients by calculating a series of Fourier integrals of the signal. As illustrated for the A 1 ∑ u + electronic state of Na 2, the method faithfully reconstructs the time-dependent complex wave function of the nuclear motion. Moreover, using perturbation theory to connect the excitation pulse and the material expansion coefficients, our method is used to determine the electromagnetic field of the excitation pulse, thus providing a simple technique for pulse characterization that obviates the additional measurements and iterative solutions that beset other techniques. The approach, which is found to be quite robust against errors in the experimental data, can be readily generalized to the reconstruction of polyatomic vibrational wave functions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.027
Threshold uncertainty score0.338

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.243
Teacher spread0.225 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2012
Admission routes1
Has abstractyes

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