Effects of nonlinear interfacial kinetics and interfacial thermal resistance in planar solidification
Bibliographic record
Abstract
Large temperature discontinuities were recently measured at a solid-liquid interface during heat transport processes. These observations suggest that when heat flows between two phases, the interface is not well characterized by assuming thermal equilibrium. This can be of importance in rapid solidification processes. In this paper we consider a planar front model that solidifies from its undercooled melt. We use a generalized interfacial boundary condition that includes nonlinear kinetic effects and allows for a temperature discontinuity. The effects of the new boundary condition on the solidification rates and the temperature profile are reported as a function of time. Our analysis shows that the undercooling regime where constant phase-front velocities are observed at steady states (traveling-wave solutions) are unaffected by the new boundary conditions. These solutions arise when the Stephan number is larger than 1. On the other hand, the solidification rates and the steady-state velocities are greatly affected by the assumed conditions at the interface. Incorporation of an interface thermal resistance, or Kapitza resistance, generates temperature discontinuities at the interface, leads to reduced solidification rates and the Mullins-Sekerka instability arises at longer wavelengths deformation of the planar front.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".